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The journey of mastering materials

Introduction
A watch’s case is both its adornment and its armour. Its weight, texture, colour, aesthetics and physical language are determined by the material from which it is made. From gold and rubber to ceramics, steel and stone, each material endows it with unique properties. This article tells the story of some of these materials and highlights their place within the Audemars Piguet collections.

1

Daily survival

Right from the design stage, the materials used in a watch case must be chosen to ensure that it will last for decades, if not centuries, strapped to our wrists and thus exposed to scratches, humidity, heat, oxidation as well as impacts. Materials’ physical and chemical properties are therefore essential.

Among these, hardness is a key criterion: the harder the case material, the less likely the watch will be damaged by scratches or impacts – yet the more difficult it will be to manufacture.

Ductility is also crucial. This is the ability of a material to bend without breaking, referred to in everyday language as flexibility or malleability. Gold, for example, is very ductile, making it the perfect material for jewellery and watches.

Elasticity is a little different. It’s the ability of a deformed material to return to its original shape and size. The original technical term is resilience. While elasticity is essential in certain movement components, it can also play a role in watch cases, particularly those made from Bulk Metallic Glass (BMG), a material that resists scratches and shocks with astonishing resilience.

Finally, there is weight, or more precisely density: a kilo of feathers weighs the same as a kilo of lead. While lightness was long regarded as the absence of value, perceptions are currently shifting in this respect.

Other key criteria are corrosion resistance and biocompatibility. A watch must not rust, oxidise or cause skin allergies.

Material Vickers hardness (HV) Density (g/cm3) Elasticity (Young's modulus GPa) Scratch resistance Melting point
(°C)
Gold (18ct) 140-230 15-16 90-110 Good 890-1150
Silver 60-80 10-11 80-90 Average 820-890
Platinum 90-140 19-21 170-190 Average 1800-1900
Tantalum 90 16,6 175-190 Average >3000
316L stainless steel 200-350 7,9 190-250 Good 1300-1500
Titanium (grade 5) 300-380 4,5 105-120 Very good 1600-1700
Forged carbon >50 1,9 40-150 Average N/A
Ceramics >1200 5,6-6 200-250 Excellent >2500
Brass 90-170 8,4 80-130 Average 880-900
Alacrite 385 8,4 210-220 Very good 1300
Cermet >1500 5-10 depends on the formulation Excellent depends on the formulation
Tungsten >2000 18-20 360-410 Excellent >3000
Rubber N/A 0,9-1,1 2-5 Excellent N/A
BMG 500 9,3 80 Excellent 550
Diamond MAX = 10 Mohs) 3,5 >1000 Excellent >3000
Turquoise 6 Mohs 2,6-2,9 N/A Excellent N/A

This table shows the main properties of the different materials. Knowledge of these properties is essential in the development and production of a watch. The choice of material is crucial, as it will affect the object’s entire life. A watch has to make its way through decades or even centuries and is put to a severe test on a daily basis.

2

A story in three acts

The idea that precious materials have always been used for Haute Horlogerie watches is a common misconception. Before industrialisation, however, a watch was inherently luxurious, whatever its material. While gold and platinum reigned supreme in luxury watchmaking from the 1800s onwards, high-tech materials made their entry in the 1970s and began progressively conquering more and more territory.

Act I. From Stone Age to Brass Age (14th – 19th centuries)

The very first clocks were made of iron, clad in the stone composing the bell tower. Wall clocks were subsequently fitted with cabinets often made of wood, brass or bronze and sometimes covered in tortoiseshell... However, as soon as the time came to consider moving timepieces around and later transporting them – whether table clocks, carriages or pocket watches – watchmakers almost invariably decided to attire them in metal that was rarely of the precious kind.

Act II. The era of noble materials (19th century – 1970s)

Pocket watches from the 17th and 18th centuries were often made of brass. To enhance their value, watchmakers sometimes embellished them with enamel, silver or fine stones. Gold made a modest appearance in the 17th century on the bezels of some enamelled watches. It was not until the mid-18th century that cases made entirely of gold gradually became the norm. From the Industrial Revolution onwards, gold was adopted as the undisputed token of prestige in Haute Horlogerie, in contrast to other watches that were then becoming more widely available.

Act III. New diversity (from the 1970s onwards)

Gold lost its monopoly on luxury in the 1970s. Audemars Piguet ennobled steel in 1972. Profoundly shaken by the quartz crisis, traditional watchmaking reinvented itself by introducing high-tech materials like titanium, ceramics, carbon and bulk metallic glass (BMG), as well as reinterpreting materials hitherto little used in watchmaking, such as granite, plastic, rubber and even wood.

3

Natural stone cases

Every culture and every period has associated symbolic values with stones, based on their rarity, their myths, their brilliance and their colours.

From the Renaissance onwards, when artisans sought to enhance their timepieces with precious materials, they often chose rock crystal, jasper, agate or sapphire.

Common in the 17th and 18th centuries, watches with partial stone exteriors subsequently became rarer. They reappeared during the Art Deco period and again in the 1960s and 1970s. In the early 21st century, Audemars Piguet went so far as to produce watch baseplates in natural stone.

While small natural inclusions make stone watches beautiful, they also render them fragile. To shape a stone without splitting or breaking it, artisans use special grinding wheels and lathes keeping vibrations to a minimum. Despite this, a significant proportion of watch cases still break before they are finished.

4

Silver, the forerunner of noble metals

Both lighter and more supple than gold yet more sensitive to oxidation, silver was historically the first precious metal to conquer the world of Haute Horlogerie. From the 16th to the 19th centuries, it appeared in finely engraved versions. Artisans often chose to use it for dials and more rarely for cases.

Silver gave way to gold in the high-end segment, meaning that by the 1900s, it occupied the niche mid-way between chrome-plated metal watches and those made of precious metals. It was the introduction of stainless steel that dealt the final blow in the 1930s.

Nonetheless, thanks to its more affordable price than gold, silver long remained the preferred material for apprentice watchmakers when it came to adorning the "school watch"  representing the culmination of their training. It is thus no coincidence that back in 1769, Joseph Piguet, great-grandfather of Audemars Piguet’s co-founder, chose it for the watch he made to earn the “Maîtrise” (master-watchmaker title).

5

Gold, the king of metals

A quintessentially noble metal, gold has been at the heart of civilisations since Antiquity. A repository of value and a standard for trade exchanges, it was used to make coins and prestigious objects. Rare, shiny, stainless, biocompatible, heavy, stable and easy to work with, it is the embodiment of wealth, success and sunshine.

Pure (24-carat) gold is too malleable to be used in watchmaking. Watch cases are therefore often made of 18-carat gold, meaning they contain 75% gold. While the United States and Nordic countries have long appreciated 14-carat gold which contains 58.5% of the precious material, 9-carat gold with a maximum content of 37.5 % is also available.

These proportions must be authenticated by hallmarks. On the other hand, the additional metals used may vary according to the period and the brand, as well as naturally depending on the desired colour. Obtaining white gold involves adding silver, palladium or previously nickel; while gold, copper and silver are used to make pink gold. This means that when a gold watch case becomes a little oxidised, that’s simply because of the silver or copper it contains...

From the mid-20th century onwards, alloys were standardised so as to always obtain the same colours, codenamed 2N, 3N, etc. However, since the 2000s the watch industry has once again sought diversity, introducing new formulae for obtaining different shades. Examples include Rolex's "Everose", Omega's "Sedna" and "Moonshine", and Hublot's "Magic Gold". In 2024, Audemars Piguet introduced "sand gold", whose reflections vary according to the light, ranging from pink to grey, with shades of blue and even brown.

Metal Yellow gold (BA) Pink gold (OR) White gold (BC) Sand gold (SG)
Gold (Au) 750 750 750 750
Copper (Cu) 125 205 95 190
Silver (Ag) 125 45 30 0
Palladium (Pd) 0 0 125 60
6

Platinum, a powerful argument

Discovered in Colombia in the 18th century, platinum is the heaviest non-radioactive metal. A diminutive of the Spanish word plata (silver), its name means "little silver". It is said that Colombian gold miners originally considered it so worthless that they threw the nuggets back into the river, thinking they were gold that had not yet matured.

Platinum's physical properties made it ideally suited to the industrial world. Corrosion-resistant, hypoallergenic and highly malleable, it only melts at around 1800°C (compared with 1000°C for gold). It came to be used in chemistry, medicine and the electronics industry.

In watchmaking as a whole and particularly for Audemars Piguet, platinum experienced its first phase of popularity during the Art Deco period. Watchmakers and jewellers created small masterpieces – miniature wristwatches, ring-watches, brooches and pendants – often embellished with rubies and diamonds.

Platinum also made its mark on the 1980s. It can be found in Audemars Piguet watches with complications, including tourbillons and double complications. When a limited edition comes in several materials, one can be pretty sure that the rarest iteration is the one in platinum!

At first glance, when polished, platinum looks like steel or silver. It is however rarer than gold and features a unique gleam. Jewellers have adopted it because it lends itself well to gemsetting, while its colour and brilliance make a good match with those of diamonds. The most notable difference is its weight: by way of example, the 1997 Royal Oak Offshore 25721PT weighs almost half a kilo!

7

1930–1970, steel blurs the lines

Steel has been around for thousands of years and has now supplanted iron. We nonetheless sometimes forget just how recent this change is. Although humankind began to master steel in the 18th century, iron long remained the symbol of the Industrial Revolution. While Brooklyn Bridge (1869) and the Eiffel Tower (1889) are made of iron, the frame of the Empire State Building (1930) is made of steel.

Whereas watchmakers long reserved iron and steel for certain movement components, everything changed with the Industrial Revolution. To reduce the price of watch cases, several ferrous alloys were introduced, such as argentan and chromium-plated brass, followed in the 1870s by burnished steel, also known as "gun metal” and whose black oxidation forms a protective layer.

In the 1910s, British and German steelmakers discovered that adding chromium rendered steel stainless. Within a few decades, stainless steel replaced silver and chromium-plated metal in the mid-range market, becoming the metal of choice for sports watches.

Steel nonetheless remained rare in the field of Haute Horlogerie. Between 1934 and 1962, for example, Audemars Piguet produced 82 chronograph wristwatches in steel, with a few selfwinding models as of 1956. The turning point came in 1972.

8

The world’s most expensive steel watch

In the 1970s, steel was par of the brief when Audemars Piguet's Italian, Swiss and French agents asked then head of the company Georges Golay to create an unprecedented watch that was at once sporty and luxurious, elegant and casual, equally suitable for chairing a Board of Directors as when sailing. It was the material of sports watches. The question was: how could it be made as precious as gold?

The answer lays in one word: complexity. The Royal Oak designed by Gérald Genta is packed with countless geometric details and finishes. Polished 45-degree bevels on the bezel, curved facets, gradual chamfering of the case middle, satin-brushed curves on the sides, a tapering bracelet... Never had so much care been devoted to steel, to the point where it almost became a noble material.

One of the first advertisements produced by Audemars Piguet's agency at the time, Hugo Buchser, referred to stainless steel as "the noble metal of modern cathedrals". The public response was swift: despite being more expensive than some gold watches, the Royal Oak was a huge success. Find out more here.

This innovation would not go unnoticed, as in the years that followed, other prestigious watch industry names including Patek Phillipe and IWC perceived the value of steel in the top-of-the-range segment and also embarked on the adventure.

9

Four decades of new materials

From the mid-1970s onwards, the tidal wave of electronic watches threatened the very existence of Swiss watchmaking. In order to reinvent itself, the industry developed new shapes, new functions and new materials, with Audemars Piguet, Omega, Tissot and Zenith at the forefront. Before looking at the main materials in the following chapters, here is a list of key dates from 1970 to 2010:

-1970. Titanium is introduced by Omega (Seamaster) and Citizen (X8 Titanium)

-1972. Steel is given a new status by Audemars Piguet (Royal Oak)

-1977. Steel and yellow gold two-tone combination, by Audemars Piguet (Royal Oak),

-1980. Rubber straps, by MDM (Hublot)

-1981. Gold-plated steel, by Audemars Piguet (Pyjamas)

-1982. Ceramic, first by Zenith and later popularised by Rado from 1986 onwards

-1983. Plastic, by Swatch (Swatch)

-1985. Granite, by Tissot (Rockwatch)

-1986. Meteorite dial, by Corum

-1988. Tantalum, by Audemars Piguet (Royal Oak and Huitième)

-1989. Wood, by Tissot (Woodwatch)

-1990. Fine stone crystal, by Audemars Piguet (Baroque)

-1993. Rubber-coated metal, by Audemars Piguet (Royal Oak Offshore)

-2002. Alacrite, by Audemars Piguet (Royal Oak Concept)

-2007. Forged carbon, by Audemars Piguet (Royal Oak Offshore)

-2010. Cermet, by Audemars Piguet

-2010. BMG, by Omega under the name "liquidmetal ©".

10

Titanium, as light as it is hard

Featuring a hardness comparable to that of tempered steel, titanium is almost twice as light and not susceptible to scratching, while also resistant to corrosion. Discovered in the 18th century, it made a modest and discreet watch industry debut during the 1930s in a balance-spring alloy named Durinval. It was subsequently used to colour synthetic sapphires, but above all to harden cutting tools.

In gained prestige in the 1960s however, equipping the Apollo rockets and forming the hull of the American Lockheed ST-71 Blackbird stealth aircraft. In 1970, Omega and Citizen simultaneously presented the first titanium watches. In 1986, Audemars Piguet decided to introduce titanium into the very heart of the watch movement. Both light and robust, it formed the carriage of the first-ever selfwinding tourbillon, Model 25643.

In 1998, the Royal Oak Offshore 25721 was made in titanium for the first time. The aim was to offer a lightweight version of this oversized watch weighing 220 grams in its steel version and 410 grams in gold. Titanium reduced the case weight to a mere 150 grams. It was an immediate success, with nearly 3,000 sold between 1998 and 2014.

The production of titanium cases implied adapting expertise, as this metal catches fire at relatively low temperatures. The first experiments in the workshops left some searing memories! Since the early 2000s, titanium has been a consistent part of the Audemars Piguet catalogue.

The watch industry mainly uses titanium grades 1 to 5 (according to the ASTM standard). Each has its own qualities and flaws. The most common is titanium grade 2, which is light and corrosion-resistant. The one used by Audemars Piguet is an alloy called "grade 5", or TA6V, featuring a good balance between hardness, density and weldability.

11

Tantalus: dark, heavy and rare

Almost as hard as steel and almost as heavy as gold, tantalum is ductile, ultra-resistant to acids, biocompatible as well as a good conductor of heat and electricity. It is notably found in surgical instruments, implants, electronics, etc.

Tantalum quietly entered the watchmaking world in the 1930s via cutting tools and mainspring alloys, then spread to quartz watches in the form of capacitors.

In the 1970s and 1980s, several celebrities reportedly expressed the wish to wear a black Royal Oak. Karl Lagerfeld himself had his Royal Oak 5402 blackened, probably using a technique known as cataphoresis. The kings of Greece and Spain entrusted their London armourer with the task of colouring their Royal Oak so that, like their firearms, it would no longer reflect the sun's rays while they were hunting.

Before the introduction of PVD treatments, blackening techniques were unable to achieve the finishing qualities demanded by Audemars Piguet. With its bluish anthracite colour embedded in the metal, tantalum offered an attractive aesthetic alternative. But where could it be found? This metal was not only difficult to source, but also to work with in terms of production.

In 1988, Audemars Piguet introduced tantalum in the cases of several models, including a Royal Oak created with golfer Nick Faldo (14486) and a chronograph named "Eighth". The adventure reached a climax in 2012, with three Royal Oak limited editions in partnership with Lionel Messi (26325), combining tantalum with pink gold, steel and platinum. By this time, PVD blackening had been fully mastered and black ceramic components were in full swing. Not particularly scratch-resistant, difficult to polish and listed as a conflict mineral in 2021, tantalum is no longer used by Audemars Piguet.

12

Rubber is no luxury

Since its introduction by Hublot in 1980, rubber has primarily been used for sports watch straps. This is hardly surprising, given that it is waterproof, flexible, comfortable and can be coloured and shaped as desired.

Its use on cases is much rarer. The story begins in 1990, when a suggestion was made for the Royal Oak Offshore that was still in the development phase at the time: namely protecting its pushers and crown by covering them with rubber. The story is told here. While the idea was simple, putting it into practice proved so difficult that the launch of the watch initially slated for 1992 had to be postponed until the following year. The Jura-based company Pibor (BIWI), which developed this technology, explored uncharted territory by guaranteeing perfect adhesion between metal and rubber, shape retention, as well as enduring resistance to wear, water and temperature changes.

In 2001, Audemars Piguet went one step further by rubber-coating the bezel. While the latter is indeed the component that endures the most scratches and knocks, when gold is completely concealed under a layer of rubber, the principle is way more than merely functional! The idea may well have seemed crazy, yet the success of Model 25940OK exceeded all expectations.

By the end of the 2000s, ceramic bezels had won the day over rubber, offering superior decorative possibilities while remaining virtually scratch-proof.

13

Ceramics

Hypoallergenic, colourfast, lighter and harder than steel, ceramics seems to have it all.

This material first appeared in the field of horology during the 18th century, notably on French clocks embellished with Meissen porcelain. It was used again in the 1960s, when German, English and then Taiwanese wall clocks made their way into our kitchens.

Although it bears the same name, high-tech ceramics is quite different, involving perfectly calibrated, homogeneous grains of Zirconium Oxide. Harder and more efficient, it entered the watch industry through movement components: prototype balance springs in the 1960s, electronic watch capacitors and then ball bearings. In 1982, Zenith created the first ceramic watch case, a material popularised by Rado in 1986.

Traditionally, ceramics is hot-moulded, yet deemed too hard to be cut. Audemars Piguet introduced it in the Royal Oak Offshore Barichello in 2006. With its partner Bangerter, the brand developed techniques for machining ceramics and producing top-of-the-range finishes: brushing, chamfering and diamond-finishing. A decade of development resulted in the first all-ceramic Royal Oak. The 26579CE model was a huge success, paving the way for white, then coloured blue, brown and even polychrome ceramics...

14

Cermet, the best of both worlds

While metal alloys have been known since the dawn of time, mixing metal with ceramics remains atypical. Cermet combines CERamic and METal. The aim? To offer the hardness of ceramics, its resistance to abrasion, corrosion and extreme temperatures, while retaining metal’s flexibility (ductility) and shock-resistance.

Discovered in 1923, cermet has been interpreted in many variants. It is found in gas turbines and in the heat shields of space shuttles. In the watch industry, cermets appeared during the 1960s, not in watches, but rather in the machines used to make them. As a cutting tool, they were unrivalled.

In 2010, Audemars Piguet set about creating cermet watch exteriors. They were so hard that they were almost impossible to scratch... So hard that they had to be moulded and could not be brushed. Watchmakers therefore chose to confine this metal to Royal Oak bezels, as they are the parts most exposed to scratches. Between 2010 and 2012, a handful of limited editions were created, including two in partnership with racing drivers Jarno Trulli and Michael Schumacher, as well as a one-of-a-kind model intended for a charity auction.

15

Carbon, forged or woven?

Watchmakers use carbon in two different ways. The most classic is woven carbon fibre. Very long strands of carbon are woven together to form an easily recognisable fabric. This technique borrowed from the automotive world made its first foray into watchmaking in 1998, on the dial of a TAG Heuer watch and on the case of Candino's Carbon Watch.

The second method is called forged carbon. Here, the carbon strands are much shorter and arranged randomly in a resin, so that resistance to torsion is optimal in all directions. Initially used in the aerospace industry, forged carbon was introduced by Audemars Piguet in 2007 on the Royal Oak Offshore Alinghi Team chronograph.

This watch made for the crew of the Swiss boat Alinghi is particularly light and easy to read. The team won the America's Cup, one of the world's most important sailing competitions, giving an extraordinary boost to the brand as well as to forged carbon. Numerous models followed, including the Millenary Carbone One, weighing less than 70 grams.

Forged carbon set a precedent and Richard Mille took the idea a step further in 2010 by creating the world's lightest wristwatch in collaboration with Audemars Piguet Renaud Papi. The RM027 combining carbon with layers of quartz (glass fibres) and worn by tennis player Rafael Nadal weighed a mere 20 grams (without the strap). In just over a decade, dozens of carbon watch variants were developed by Hublot, Panerai, Roger Dubuis, Zenith, Breitling, Girard Perregaux Oris, IWC, Bulgari...

16

BMG, metal with a bounce

Metallic glass – or BMG for Bulk Metallic Glass – is a metal that is both very hard and elastic, while also particularly popular in the fields of micromechanics and top-level sports.

There are several types of BMG, because the alloy itself is less important than the manufacturing process when it comes to obtaining this astonishing metal. In the 1960s, researchers discovered that when a metal heated to a liquid state was cooled very suddenly, its structure did not have time to reconstitute itself normally. The molecules freeze so quickly that they retain the disorder of their liquid state – which is very similar to the crystalline structure of glass. BMG is therefore a metal with a glass-like structure.

BMG is greatly valued in the watch industry because the metal obtained is so hard that it is almost scratch-proof. Moreover, if the case sustains a small impact, its elasticity enables an instant return to its original shape.

Introduced by Omega in 2010 and adopted by Panerai, BMG can take different forms. The alloy used by Audemars Piguet since 2021 is the first to be based on precious metals. Palladium gives it high resistance to wear and corrosion, as well as enhanced brilliance. While at first glance, it resembles platinum, BMG is both lighter and stronger.

17

Chroma, or the marriage of colours

The same material may have several different colours. Ceramics, for example, can be blue, green or black... However, until now, each component had a single uniform colour, because each one begins by being formed at such a high temperature that it melts and all the elements it contains blend together before hardening as it cools. This is somewhat like a syrup that hardens as it freezes. The traditional method of combining them afterwards is to weld or glue the components together.

In 2019, Audemars Piguet's materials engineers took on the chroma project. The aim was to create components juxtaposing several colours, or even several materials, while remaining perfectly homogeneous. The method is called "SPS", for Spark Plasma Sintering. Notably used in the aerospace industry, SPS technology bonds materials so intimately that they become totally inseparable, while remaining visually and physically distinct.

In 2024, Audemars Piguet presented the first results of this research, including the first polychrome ceramic prototype, as well as watch prototypes combining different-coloured golds. This heralds a new chapter in the history of materials, opening up whole new realms of possibility.

 

Audemars Piguet Heritage Team, May 2024

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